Low Dielectric Loss Epoxy Polymer Composite From Periwinkle Shell Microparticles
Main Article Content
Abstract
The quest for improved polymeric insulation to achieve a compact and
reliable electrical and electronic power equipment design brings about the idea of composite polymeric insulation. Emphasis has been on chemically synthesised metal oxide nanoparticles. This paper presents the dielectric behaviour of epoxy polymer composite with microparticles with an average particle size of about 4.3 μm from the periwinkle shell.
The changes in the relative permittivity and dielectric loss of the polymer with the periwinkle shell composite metal oxides at low filler concentrations were studied over a frequency range
from 200 Hz to 100 kHz. The results showed that the polymer composite exhibits dielectric characteristics that are quite different when compared with the earlier observed results for polymer micro-composites. Unlike the usual expectations of increasing dielectric loss with increasing filler concentration in polymer micro-composites, the dielectric response of the
epoxy-shell microparticle powder composite displayed a decrease in the dielectric loss with micro-filler concentration. The 1 wt% periwinkle shell microparticle epoxy composite has a dielectric loss lower than that of 0.5 wt% Al2O3 nanoparticle epoxy composite. This suggests that the waste periwinkle shell can serve as a cheap resource to produce low-cost
polymer composite with improved electrical insulation properties.
Article Details

This work is licensed under a Creative Commons Attribution 4.0 International License.
References
Nelson, J. K. & Hu, Y. (2005). Nanocomposite dielectrics—properties and
implications. J. Phys. D Appl. Phys., 38, 213–222. https://doi.org/10.1088/0022-3727/38/2/005
Donzel, L. & Schuderer, J. (2012). Nonlinear resistive electric field control for
power electronic modules. IEEE Trans. Dielect. Elect. Ins., 19(3), 955–959.
https://doi.org/10.1109/TDEI.2012.6215099
Abdelmalik, A. A., Nysveen, A. & Lundgaard, L. E. (2016). Partial discharges in
liquid embedded power electronics: Effects of pressure and liquid nature under
negative pulse voltage stress. IEEE Trans. Dielect. Elect. Ins., 23(2), 1119–1125.
https://doi.org/10.1109/TDEI.2015.005615
Hui, L. et al. (2009). Electrochemical treeing in XLPE/silica nanocomposites.
Paper presented at the 2009 IEEE Conference on Electrical Insulation and
Dielectric Phenomena, Virginia, 18–21 October. https://doi.org/10.1109/CEIDP.2009.5377858
Shah, K. S. et al. (2009). High-density polyethylene (HDPE) clay nanocomposite
for dielectric applications. IEEE Trans. Dielect. Elect. Insul., 16(3), 853–861.
https://doi.org/10.1109/TDEI.2009.5128526
Wang, H. W. et al. (2007). Effect of clay on properties of polyimide-clay
nanocomposites. J. Appl. Pol. Sci., 318–324. https://doi.org/10.1002/app.25740
Boyle, M. A., Martins, C. J. & Neuener, J. D. (2001). Epoxy resins in composites.
In Miracle, D. B. & Donaldson, S. L. (Eds.), ASM handbook. New York: ASM
International, 78–89. https://doi.org/10.31399/asm.hb.v21.a0003362
Tuncer, E. et al. (2007). Enhancement of dielectric strength in nanocomposites.
Nanotechnol., 18, 325704. https://doi.org/10.1088/0957-4484/18/32/325704
Zhang, C. & Stevens, G. C. (2008). The dielectric response of polar and non-
polar nanodielectrics. IEEE Trans. Dielect. Elect. Insul., 15(2), 606–617.
https://doi.org/10.1109/TDEI.2008.4483483
Singha, S. & Thomas, M. J. (2008). Permittivity and tan delta characteristics
of epoxy nanocomposites. IEEE Trans. Dielect. Elect. Insul., 15(1), 106–117.
https://doi.org/10.1109/T-DEI.2008.4446731
Singha, S. & Thomas, M. J. (2008). Reduction of permittivity in epoxy
nanocomposites at low nano-filler loadings. Paper presented at 2008 Annual
Report Conference on Electrical Insulation Dialetric Phenomena, 26–29 October,
Quebec City, Canada, 726–729.
Lan, T. & Pinnavaia, T. J. (1994). Clay-reinforced epoxy nanocomposites.
Chem. Mater., 6, 2216–2219. https://doi.org/10.1021/cm00048a006
Zi-Rui, J. et al. (2018). Effects of filler loading and surface modification
on electrical and thermal properties of epoxy/montmorillonite composite.
Chin. Phys. B, 27(11), 117806. https://doi.org/10.1088/1674-1056/27/11/117806
Abdelmalik, A. A. & Sadiq, A. (2019). Thermal and electrical characterization of
composite metal oxides particles from periwinkle shell for dielectric application.
SN Appl. Sci., 1, 373. https://doi.org/10.1007/s42452-019-0388-5
Von Hippel, A. R. (1954). Theory in dielectric materials and applications.
Massachusetts: MIT Press.
Singha, S. & Thomas, M. J. (2008) Dielectric properties of epoxy nanocomposites.
IEEE Trans. Dielect. Elect. Ins., 15(1), 12–23. https://doi.org/10.1109/T-DEI.2008.4446732
Kadhim, M. J. et al. (2014). Dielectric properties of epoxy/Al2O3 nanocomposites.
Int. J. Appl. Inn. Eng. Manage., 3(1), 468–477.